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Synthesis of amine incorporated hierarchical metal organic framework (MOF) MIL-101(Cr)/SBA-15, meso/ micro-porous composites, with tailored properties for CO 2 capture is reported. The synthesized composites were characterized in terms of their crystallinity, morphology, functional groups, and textural properties. Isothermal adsorption of CO 2 from concentrated sites as well as ambient conditions were evaluated by gravimetric and volumetric measurements. The optimized composite i.e., MIL-101(Cr)/SBA-15/PEI-25 showed improved pseudo- equilibrium adsorption capacity of 3.2 mmol/g at 303 K and 1 bar, compared to nascent SBA-15 (0.8 mmol/g) and the MOF, i.e., MIL-101(Cr) (1.3 mmol/g). Such adsorption performance can be attributed to the basic sites of the impregnated polyethyleneimine (PEI), unsaturated Cr(III) metal sites, and the hierarchical pore structure of the composite which imparts chemical as well physical adsorption forces towards CO 2 lower amine loading of 25 wt% in the composite resulted in facile CO 2 uptake. Interestingly, desorption at much lower temperature of